Dendrite-Embedded Platinum–Nickel Multiframes as Highly Active and Durable Electrocatalyst toward the Oxygen Reduction Reaction

Extra Form
author Kwangyeol Lee
Homepage http://nanolab.korea.ac.kr/
journal Nano Lett., Article ASAP(DOI: 10.1021/acs.nanolett.8b00270)
?

Shortcut

PrevPrev Article

NextNext Article

ESCClose

+ - Up Down Comment Print

 

 

권혁부.jpg                            박종식.png

                                               Hyukbu Kwon (석사과정)                   Jongsik Park (박사과정)

 

Pt-based nanoframe catalysts have been explored extensively due to their superior activity toward the oxygen reduction reaction (ORR). Herein, we report the synthesis of Pt–Ni multiframes, which exhibit the unique structure of tightly fused multiple nanoframes and reinforced by an embedded dendrite. Rapid reduction and deposition of Ni atoms on Pt–Ni nanodendrites induce the alloying/dealloying of Pt and Ni in the overall nanostructures. After chemical etching of Ni, the newly formed dendrite-embedded Pt–Ni multiframes show an electrochemically active surface area (ECSA) of 73.4 m2 gPt–1 and a mass ORR activity of 1.51 A mgPt–1 at 0.93 V, which is 30-fold higher than that of the state-of-the-art Pt/C catalyst. We suggest that high ECSA and ORR performances of dendrite-embedded Pt–Ni multiframes/C can be attributed to the porous nanostructure and numerous active sites exposed on surface grain boundaries and high-indexed facets.

 

 

pic.jpg

 

https://pubs.acs.org/doi/10.1021/acs.nanolett.8b00270

 


Articles

1 2 3 4 5 6 7 8

Designed by sketchbooks.co.kr / sketchbook5 board skin

나눔글꼴 설치 안내


이 PC에는 나눔글꼴이 설치되어 있지 않습니다.

이 사이트를 나눔글꼴로 보기 위해서는
나눔글꼴을 설치해야 합니다.

설치 Cancel

Sketchbook5, 스케치북5

Sketchbook5, 스케치북5

Sketchbook5, 스케치북5

Sketchbook5, 스케치북5