Gradients of Rectification: Tuning Molecular Electronic Devices by the Controlled Use of Different-Sized Diluents in Heterogeneous Self-Assembled Monolayers

Extra Form
author Hyo Jae Yoon
journal Angew. Chem. Int. Ed. 2016, Early View (DOI: 10.1002/anie.201604748)
?

Shortcut

PrevPrev Article

NextNext Article

ESCClose

+ - Up Down Comment Print

Molecular electronics has received significant attention in the last decades. To hone performance of devices, eliminating structural defects in molecular components inside devices is usually needed. We herein demonstrate this problem can be turned into a strength for modulating the performance of devices. We show the systematic dilution of a monolayer of an organic rectifier (2,2′-bipyridine-terminated n-undecanethiolate) with electronically inactive diluents (n-alkanethiolates of different lengths), gives remarkable gradients of rectification. Rectification is finely tunable in a range of approximately two orders of magnitude, retaining its polarity. Trends of rectification against the length of the diluent indicate the gradient of rectification is extremely sensitive to the molecular structure of the diluent. Further studies reveal that noncovalent intermolecular interactions within monolayers likely leads to gradients of structural defect and rectification.

 

toc (2).jpg

 

http://onlinelibrary.wiley.com/doi/10.1002/anie.201604748/full


Articles

3 4 5 6 7 8

Designed by sketchbooks.co.kr / sketchbook5 board skin

나눔글꼴 설치 안내


이 PC에는 나눔글꼴이 설치되어 있지 않습니다.

이 사이트를 나눔글꼴로 보기 위해서는
나눔글꼴을 설치해야 합니다.

설치 Cancel

Sketchbook5, 스케치북5

Sketchbook5, 스케치북5

Sketchbook5, 스케치북5

Sketchbook5, 스케치북5